Electrical Transport Phenomena in Molten Salts
ثبت نشده
چکیده
The equivalent conductivity of molten salts containing more than two ion constituents will be discussed using the equivalent fractions (Äquivalentanteile). The ionic conductivities of the ion constituents follow from this equivalent conductivity and the transport numbers. The electrical transport phenomena are referred to the idealized ionic melt which is defined by the limiting values of the ionic conductivities of the ion constituents in the pure components. The equations are calculated for the system K N 0 3 + A g N 0 3 .
منابع مشابه
The Electrical Conductivity and Density of Solid and Molten Li2S04 —Ag2S04
The electrical conductivity of solid and molten Li2S04 —Ag,S0 4 has been measured for different concentration values. Density measurements of molten Li2S04 , Ag2S04 and equimolar (Li, Ag) 2S0 4 show that the system can be considered ideal. The equivalent conductivity of molten (Li, Ag) 2S0 4 can be calculated from the conductivities of the pure salts by assuming that the cations are moving in g...
متن کاملEffect of Frit Material on External Transport Numbers in Molten Salts
für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...
متن کاملIon atmosphere relaxation controlled electron transfers in cobaltocenium polyether molten salts.
A room-temperature redox molten salt for the study of electron transfers in semisolid media, based on combining bis(cyclopentadienyl)cobalt with oligomeric polyether counterions, [Cp2Co](MePEG350SO3), is reported. The transport properties of the new molten salt can be varied (plasticized) by varying the polyether content. The charge transport rate during voltammetric reduction of the ionically ...
متن کاملInterplay between structure and transport properties of molten salt mixtures of ZnCl2-NaCl-KCl: A molecular dynamics study.
Molten mixtures of network-forming covalently bonded ZnCl2 and network-modifying ionically bonded NaCl and KCl salts are investigated as high-temperature heat transfer fluids for concentrating solar power plants. Specifically, using molecular dynamics simulations, the interplay between the extent of the network structure, composition, and the transport properties (viscosity, thermal conductivit...
متن کاملStructural Relaxations in a Simple Model Molten Salt
The structural relaxations of a dense, binary mixture of charged hard spheres are studied using the Mode Coupling Theory (MCT). Qualitative differences to non–ionic systems are shown to result from the long–range Coulomb interaction and charge ordering in dense molten salts. The presented non–equilibrium results are determined by the equilibrium structure, which is input using the well studied ...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره شماره
صفحات -
تاریخ انتشار 2012